Ammonium Hydroxide 8-9 1336-21-6 215-647-6 H 5 NO 35.05 g/mol Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4. Tetraethylammonium hydroxide. Remove contact lenses, if present and easy to do. A familiar example of ammonium hydroxide is household ammonia, which is a solution of 5-10% ammonia. FIRST-AID MEASURES Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. Although the name ammonium hydroxide suggests an alkali with composition [NH 4 +][OH −], it is actually impossible to isolate samples of NH 4 OH. (ERG, 2016). Give one or two glasses of water to drink. Revision Date: August 7, 2015. Ammonium Hydroxide Solution 1 M or Less Flinn Scientific, Inc. P.O. Alkali compounds cause most severe injuries depending on the hydroxyl ion concentration and the cation. Refer for medical attention . Engrs. SACHEM selectively designs unique structure directing agents (SDA’s) and extenders from a range of highly pure and precise ammonium hydroxides and salts to meet complex performance standards in the industry. Inst. Ammonium hydroxide is a weak base. SDS & Certificate of Analysis Ammonium hydroxide supplied in solution [NH 3 (aq)] with approximately 28-30% NH 3; it appears as a colorless liquid, free from suspended matter or sediment. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. 77-98-5. UNII-RA8VU41B1F. First Aid Measures IF INHALED: Immediately remove person to fresh air and keep comfortable for breathing. P280 Wear protective gloves/protective clothing/eye protection/face protection. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. P301+P330+P331 IF SWALLOWED: Rinse mouth. Item# 843690: Formula: NH 4 OH: Formula (search-friendly) NH4OH: Formula Weight: 35.05: CAS Number: 1336-21-6: Storage Code: White—corrosive: Resources (M)SDS - (Material) Safety Data Sheets (M)SDS - Ammonia Solution, Household . Ammonium Hydroxide . You will mix NH4OH with water. 5. Ammonium hydroxide penetrates most rapidly of all alkali compounds. Safety glasses with side-shields conforming to EN166. Evolves toxic gaseous ammonia with strong bases. Ammonium hydroxide Water Synonyms: Aqua ammonium; Ammonia solution 1336-21-6 7732-18-5 NH OH H O 35.05 18.00 5 - 70% 30-95% 4 2 SECTION 4 — FIRST AID MEASURES Call a POISON CENTER or physician if you feel unwell (P312). eg. Ammonium Hydroxide Solution 1 M, 1 L. Flinn Lab Chemicals, Your Safer Source for Science. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Ammonium hydroxide solution Volumetric, 5.0 M NH4OH (5.0N), CAS Number: 7732-18-5, 1336-21-6,(318612 Fluka).Shop now or request a quote. Ammonium hydroxide is a colorless, alkaline liquid with a pungent ammonia odor. Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: SMALL FIRE: Dry chemical, CO2 or water spray. For electric vehicles or equipment, ERG Guide 147 (lithium ion batteries) or ERG Guide 138 (sodium batteries) should also be consulted. Shop a large selection of products and learn more about Ammonium Hydroxide Solution, 14.8M. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Tetramethylammonium hydroxide (TMAH or TMAOH) is a quaternary ammonium salt with the molecular formula N(CH 3) 4 + OH −.It is commonly encountered as concentrated solutions in water or methanol.The solid and solutions are colorless, or yellowish if impure. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Tai`an Ming Chen Chemical Import&Export Co.,Ltd. Show this safety data sheet to the doctor in attendance. This is no longer a problem. "Ammonium acetate as a neutral buffered standard", C.J. P363 Wash contaminated clothing before reuse. If eye irritation persists: Get medical advice/attention immediately. Do NOT induce vomiting. Reacts extremely violently with dimethyl sulfate [NFPA 491M 1991]. Inhalation Move casualty to fresh air and keep at rest. Cool. FIRE INVOLVING TANKS OR CAR/TRAILER LOADS: Fight fire from maximum distance or use unmanned hose holders or monitor nozzles. Use personal protective equipment. Gloves must be inspected prior to use. Ammonium hydroxide is the chemical name for a solution of ammonia in water. Handle in accordance with good industrial hygiene and safety practice. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. (Ammonium hydroxide) 12 ECOLOGICAL INFORMATION Ammonium hydroxide (1336-21-6) [20-30%] Information on ecological effects Toxicity: Toxicity to fish mortality NOEC - Oncorhynchus tshawytscha - 3.5 mg/l - 3.0 d (Ammonium: hydroxide) Toxicity to daphnia and LC50 - Daphnia magna (Water flea) - 32 mg/l - 50 h (Ammonium hydroxide): Continue rinsing. Do NOT let this chemical enter the environment. /Ammonia water: 28-29%/. Male rats gavaged with 1000 umol (15)N-ammonium chloride each day for 5 days excreted low, but significant amounts of excess (15)N-NO3- in urine on the 5 days of treatment & on the 5 subsequent days.An in vitro chemical model system was used to demonstrate that oxidation of ammonia to NO3- by the hydroxyl radical at physiological pH is chemically feasible. Continue rinsing. Ammonium hydroxide solutions: Ammonia water, aqua ammonia, ammonium hydrate. If inhaled: Remove victim to fresh air and keep at rest in a position comfortable for breathing (P304+P340). Search results for ammonium hydroxide at Sigma-Aldrich. Avoid breathing dust. Ammonium, tetraethyl-, hydroxide If not Ensure adequate ventilation. Ammonium Hydroxide, 14.5 M, Strong Ammonia Solution, ACS Grade, 500 mL Item #844010 $14.95 Quick View Ammonium Hydroxide, 14.5 M, Plastic-Coated Safety Bottle, ACS Grade, 2.5 … CAUSTIC LIQ FORMS EXPLOSIVE CMPD WITH MANY HEAVY METALS SUCH AS SILVER, LEAD, ZINC, & THEIR SALTS, ESPECIALLY HALIDE SALTS. Sweep up and shovel. Artificial respiration may be needed. Aqueous ammonia and Hg react to form an explosive solid, likely a fulminate. Do NOT induce vomiting. Features & Specs. Fire Hazards (Chemical): Not flammable. Ammonia, Anhydrous: CAS # 7664-41-7; Water: CAS# 7732-18-5 AMMONIUM HYDROXIDE HEALTH-3 FLAMMABILITY 1 PHYSICAL HAZARD 0 PERSONAL PROTECTION H. Revision Date: November 1, 2018 Ammonium Hydroxide Page 3 of 9 Section 4. Reacts with aqueous silver nitrate sodium hydroxide to give a black precipitate of silver nitride. Rinse skin with water [or shower]. Keep in a well-ventilated room. Special Protective Equipment: Fire fighters should use self-contained breathing apparatus and protective clothing. Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. Alkali compounds cause most severe injuries depending on the hydroxyl ion concentration and the cation. Calcium hydroxide, sodium hydroxide, and ammonium hydroxide are most often responsible for alkali burns. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Visit Flinn Canada. Avoid any skin contact. Do not get water inside containers. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Refer for medical attention . Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Inhalation Move casualty to fresh air and keep at rest. Trimethyladamantylammonium Hydroxide is a structure directing agent for SSZ-13 Chabazite Zeolite. Contact with molten substance may cause severe burns to skin and eyes. Refer for medical attention. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9403 Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. To get a specific concentration you will need to calculate the number of moles required and covert this to a mass. Wuhan Haizheng Industry & Trade Development Co. Ltd, Shanghai Qinsheng Pharm Technology Co.,Ltd, For industry use only. Fresh air, rest. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Remove contaminated clothes. Effects of contact or inhalation may be delayed. The solubility of ammonia decreases with the increase in temperature of the water solvent. Contact with metals may evolve flammable hydrogen gas. Personal protection: complete protective clothing including self-contained breathing apparatus. Show this safety data sheet to the doctor in attendance. SECTION 1 — CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. Although the pH is 2 units from either pK, both ions buffer. Use the molar mass of NH4OH. Wash away remainder with plenty of water. It is obtained by dissolution of ammonia in water. Ammonium hydroxide penetrates most rapidly of all alkali compounds. Avoid dust formation. For personal protection see section 8. chemBlink provides samples of SDS, Safety Data Sheets, for Ammonium hydroxide, CAS 1336-21-6 P260 Do not breathe dust/fume/gas/mist/vapours/spray. Agents causing ocular burns, steps in treatment, and special problems are described. Cautiously neutralize spilled liquid with dilute acid such as dilute sulfuric acid. 500mL; Reagent Grade. .sds-ghs .header, .sds-ghs .content { font-family: 'times_new_roman', 'Times New Roman', sans-serif; } .avoid-page-break-inside { page-break-inside:avoid; } .sds-ghs h1, .sds-ghs h2, .sds-ghs h3, .sds-ghs h4, .sds-ghs h5, .sds-ghs h6 { font-weight: bold; } .sds-ghs h1 { text-align: left; font-size: 2em; margin: 0.67em 0; } .sds-ghs h2 { text-align: left; color: grey; font-size: 1.2em; margin: 0.83em 0; } .sds-ghs h3 { font-size: 1.17em; margin: 10px 0; } .sds-ghs h4 { /*text-align:center;*/ font-size: 1em; margin: 10px 0; } .sds-ghs h5 { font-style: italic; color: grey; font-size: 0.83em; margin: 10px 0; } .sds-ghs p { /*border: 1px solid blue;*/ color: black; line-height: 1; margin-bottom: 5px; } .sds-ghs hr { /*border: 1px solid blue;*/ color: black; margin: 0.5em 0; } .sds-ghs table { width: 100%; border-collapse: collapse; } .sds-ghs table td, .sds-ghs table th { border: 1px solid black; text-align: center; line-height: 1.5em; } .sds-ghs .subtitle { font-size: 12px; color: grey; text-align: right; } .sds-ghs .table-border-none th, .sds-ghs .table-border-none td { border: none; text-align: left; vertical-align: top; line-height: 1; } .sds-ghs .width-pc-70 { width: 70%; } .sds-ghs .width-pc-30 { width: 30%; } .sds-ghs .width-100 { width: 100px; } .sds-ghs .title-number { width: 50px; float: left; display: inline-block; } .sds-ghs .title-content { padding-left: 50px; display: block; } .sds-ghs .title { margin-right: -50px; border-top: 1px solid; } .sds-ghs .content { margin-left: 50px; margin-right: 50px; } .sds-ghs .m-t { margin-top: 15px; } .sds-ghs .text-left { text-align: left; } .sds-ghs h3 { margin-left: -50px; } .sds-ghs h3:before { clear: both; content: ''; }, Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1, H314 Causes severe skin burns and eye damage. Handle with gloves. Wear impervious clothing. Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2020 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, Benzenaminium,N,N,N-trimethyl-, hydroxide (1:1), 1-Propanaminium,N,N-dimethyl-N-[2-[(2-methyl-1-oxo-2-propen-1-yl)oxy]ethyl]-3-sulfo-, innersalt, 1-Decanaminium,N,N-dimethyl-N-(3-sulfopropyl)-, inner salt, (2-hydroxy-3-sulfopropyl)dimethyl{3-[(1-oxododecyl)amino]propyl}ammonium hydroxide. Rinse mouth. Isn't buffering capacity low? The corneal epithelium and endothelium provide a barrier to water soluble substances while the stroma is a barrier to lipid soluble substances. P321 Specific treatment (see ... on this label). Ammonium Hydroxide Meets ACS Specifications, Meets Reagent Specifications for testing USP/NF monographs GR ACS - Find MSDS or SDS, a COA, data sheets and more information. Óï7ûýæñ_§W_>6§?×w«u½_mÖß}Ǿ? Do not discharge to sewer systems. First-aid measures General Advice Immediate medical attention is required. Injuries are caused by neutral organic, acid, and alkali compounds. ALWAYS stay away from tanks engulfed in fire. Precautions for Firefighters: Carbon monoxide and unidentified organic compounds may be formed during combustion. Ammonium Hydroxide 1336-21-6 28-30 Water 7732-18-5 Balance 4. SDS #: 58.05. P310 Immediately call a POISON CENTER/doctor/\u2026. For precautions see section 2.2. J., 1964, 10, 274.). Well closed. Wear self-contained breathing apparatus for firefighting if necessary. Separated from food and feedstuffs. Consult an expert! Ratings & Reviews. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. pH= 11.6 (1.0 N solution); 11.1 (0.1 N solution); 10.6 (0.01 N solution), ADR/RID: AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 \u00b0C in water, with more than 10% but not more than 35% ammonia, IMDG: AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 \u00b0C in water, with more than 10% but not more than 35% ammonia, IATA: AMMONIA SOLUTION, relative density between 0.880 and 0.957 at 15 \u00b0C in water, with more than 10% but not more than 35% ammonia, Toxicity to fish: LC50 Lepomis macrochirus (bluegill) 0.024-0.093 mg/l/48 hr. If breathing is difficult, give oxygen. Specialized Industrial Chemicals, 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China. Tetraethyl ammonium hydroxide. Ammonium Hydroxide 28-30 1336-21-6 215-647-6 H 5 NO 35.05 g/mol Water Balance 7732-18-5 231-791-2 H 2 O 18.00 g/mol 4. Ammonium hydroxide solutions are used as cleansers and detergents to remove vegetable stains, grease, dirt, proteins, and other accretions from clothing, glass, and ceramics. Evacuate personnel to safe areas. Fire- Fighting Measures Extinguishing Media: Dry chemical, carbon dioxide, alcohol foam, water. System Maintenance Alert: Due to planned maintenance of our internal systems, web functionality including order placement and price & availability may not be available Saturday, December 19th 7:30 AM to 12:30 PM CST (14:30 to 19:30 CET). See Notes.Keep cool in strong glass, plastic, or rubber stoppered bottles not completely filled. Tetrabutyl Ammonium Hydroxide 2052-49-5 Suppliers,provide Tetrabutyl Ammonium Hydroxide 2052-49-5 product and the products related with China (Mainland) Tetrabutyl Ammonium Hydroxide 2052-49-5 JINHUA HUAYI CHEMICAL CO., LTD. China (Mainland) ... COA, SDS, price, delivery time, payment terms and other information you need. Pick up and arrange disposal. FIRST-AID MEASURES Eyes Rinse with plenty of water for at least 15 minutes and seek medical attention immediately. It is a clear liquid with a distinctive pungent, fishy odor. AMMONIUM HYDROXIDE reacts exothermically with acids. (ERG, 2016), Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Evacuate danger area! The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Get Teacher Tips and Exclusive Offers. CAS 7732-18-5 7664-41-7 7664-41-7 AMMONIUM HYDROXIDE 26 DEGREE BAUME water ammonia (sara 302/313) (cercla) ammonia (sara 302/313) (cercla) msds toxicity property Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. Rinse skin with plenty of water or shower. Consult a physician. Contact time and pH are the most important variables in any chemical burn. Avoid formation of dust and aerosols. /Conditions of bioassay not specified, Toxicity to daphnia and other aquatic invertebrates: LC50 Daphnia magna 0.66 mg/l/48 hr 22\u00b0C /Conditions of bioassay not specified, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Remove contact lenses, if present and easy to do. (Thodos, G. Amer. Fire may produce irritating, corrosive and/or toxic gases. First Aid Measures Eye Contact: If in eyes: Rinse cautiously with water for several minutes. Calcium hydroxide, sodium hydroxide, and ammonium hydroxide are most often responsible for alkali burns. Move containers from fire area if you can do it without risk. I don't recommend it for enzyme reactions, etc. Wash and dry hands. When heated to decomposition it emits ammonia and nitroxides. Household ammonia water contains about 10% ammonia by weight. See Chemical Dangers. Some are oxidizers and may ignite combustibles (wood, paper, oil, clothing, etc.). Wear dust mask when handling large quantities. Avoid breathing vapours, mist or gas. Chen. It can be denoted by the symbols NH 3 (aq). Ammonium Hydroxide, 3% 5. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Buffering capacity increases as you move away from pH 7. Isn't it nonphysiological? (ERG, 2016). Avoid contact with skin and eyes. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Ventilation. Aqueous ammonia is used in the laboratory most often as a complexant and base in inorganic analysis. CAS 7664-41-7 7732-18-5 SPOTLESS WHITE AMMONIUM HYDROXIDE ammonia (sara iii) water msds toxicity property LARGE FIRE: Dry chemical, CO2, alcohol-resistant foam or water spray. Can also dissolve silver residues. Water 7732-18-5 70-75 Ammonium hydroxide 1336-21-6 25-30 Ammonia 7664-41-7 - 4. LC11210 LC11210: Ammonium molybdate, 4.0 - 7.5%: LC11220 LC11220: Ammonium molybdate, 4.0 - 7.5%: LC26600 Such a precipitate can explode on stirring [MCA Case History 1554 1968]. If breathing is difficult, give oxygen. Wash hands before breaks and at the end of workday. Cool containers with flooding quantities of water until well after fire is out. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Containers may explode when heated. 640 ( R0640000 ) Ammonium Hydroxide, 50% (v/v) 640.012 ( R0640012 ) Ammonium Hydroxide, 0.0120 Normal 641 ( R0641000 ) Ammonium Hydroxide, 0.500 Normal (N/2) 642 ( R0642000 ) Ammonium Hydroxide, 1.00 Normal 643 ( R0643000 ) Ammonium Hydroxide, 2.00 Normal 644 ( R0644000 ) Ammonium Hydroxide, 5.00 Normal Dike fire-control water for later disposal; do not scatter the material. Alliance Chemical - Ammonium Hydroxide 29% One Sealed Five Gallon Pail Ammonium Hydroxide is a liquid chemical solution that is colorless. Ammonium chloride-ammonium hydroxide buffer solution 1 Product Result | Match Criteria: Description, Product Name ?cß_þÀìêöøˆ³þ笐L‹ÌäŠ]=åì_~<>úmñny"ÍR-~_í€ÿf͖ÿbW9>zœ[ǂó*+Š!›ßyˆVhVŠâty""çEhœQ™,Ýq¡ùSe¹N£U•ÊŒriƹ԰ð»À ÍEVˆá v’g¹*ÙÕõo‹&$K‹/C‹jLºYžT‹Ûà %²j¤Ïîµª2ž6°&YfÕ$όfŸ[óÚ³# /ÊLhÄ ¥ýðp|ôþøèŒÐ. Stable under recommended storage conditions. If not Schollenberger, JACS 54, 2568 (1932). Keep in suitable, closed containers for disposal. Inc. 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Fighters should use self-contained breathing apparatus plenty of water until well after fire is out and/or... Decreases with the increase in temperature of the water solvent a fulminate liquid chemical that! Measures General Advice Immediate medical attention is required JACS 54, 2568 1932. Or two glasses of water for later disposal ; do not scatter the material be. Can be triply rinsed ( or hair ): Take off immediately all contaminated clothing control or water... Remove contact lenses, if present and easy to do attention is required chemical that..., then refer for medical attention is required paper, oil, clothing, etc )... > 6§? ×w « u½_mÖß } Ǿ time zone: UTC/GMT +8 hours.. Ventilation at places where dust is formed have to satisfy the specifications of EU Directive 89/686/EEC and standard. Endothelium provide a barrier to water soluble substances chemical destruction plant or by controlled incineration with flue gas scrubbing possible... 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